1) David McCallum (host, appearing in character as ""Ilya Kuryakin"" from ""Man from U.N.C.L.E."") 2) Beau Brummels – ""Don't Talk to Strangers"" 3) Peter and Gordon – ""Yesterday"" 4) Brenda Lee – ""Rusty Bells"" 5) The Animals – ""We Gotta Get Out of This Place"" 6) TOP POP MEDLEY 6a) David McCallum – ""Agent Double-O-Soul"" 6b) Brenda Lee with Peter & Gordon – ""Mohair Sam"" 6c) Beau Brummels – ""Catch Us If You Can"" (end of medley) 7) The Animals – ""Club A Go-Go"" (Hullabaloo A Go-Go segment)